3,4-dimethoxychalcone induces autophagy and reduces neointimal hyperplasia and aortic lesions

Autophagy inducers can prevent cardiovascular aging and age-associated diseases including atherosclerosis. Therefore, we hypothesized that autophagy-inducing compounds that act on atherosclerosis-relevant cells might have a protective role in the development of atherosclerosis. Here we identified 3,4-dimethoxychalcone (3,4-DC) as an inducer of autophagy in several cell lines from endothelial, myocardial and myeloid/macrophagic origin, as demonstrated by the aggregation of the autophagosome marker GFP-LC3 in the cytoplasm of cells, as well as the downregulation of its nuclear pool indicative of autophagic flux. In this respect, 3,4-DC showed a broader autophagy-inducing activity than another chalcone (4,4- dimethoxychalcone), spermidine and triethylene tetramine. Thus, we characterized the potential antiatherogenic activity of 3,4-DC in two different mouse models, namely, (i) neointima formation with smooth muscle expansion of vein segments grafted to the carotid artery and (ii) genetically predisposed ApoE −/− mice fed an atherogenic diet. In the vein graft model, local application of 3,4-DC was able to maintain the lumen of vessels and to reduce neointima lesions. In the diet-induced model, intraperitoneal injections of 3,4-DC significantly reduced the number of atherosclerotic lesions in the aorta. In conclusion, 3,4-DC stands out as an autophagy inducer with potent antiatherogenic activity.

Open access paper:

https://www.nature.com/articles/s41419-023-06305-x

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This quote from the link is intriguing. “Of note, topically applied 3,4-DC also turned out to mediate beneficial effects against ultraviolet-A-induced skin damage [33]. Although this effect was attributed to the antioxidant activity of 3,4-DC, autophagy has previously been implicated in the natural and drug-induced protection of the skin against ultraviolet insult and photoaging [34,35,36]. Hence, it is possible, yet remains to be demonstrated that the skin-protective effects of 3,4-DC are secondary to local autophagy induction.”

Some related reading on 3,4 DC, and 4,4 DMC:

A Japanese relative of the carrot might hold the key to longevity, scientists have discovered.

The flowering ashitaba (Angelica keiskei) plant, traditionally used in Asian medicine, contains a flavonoid called 4,4’-dimethoxychalcone, or DMC. European researchers discovered the substance’s superior health benefits when testing 180 subclasses of flavonoids for their anti-ageing properties.

DMC was their “top hit”, as reported in the journal Nature Communications – even outperforming other known protective compounds, including resveratrol, a chemical found in red wine .

The large research team was led by Frank Madeo and Guido Kroemer from the University of Graz in Austria and the Centre de Recherche des Cordeliers in Paris, France.{%recommended 8427%}

February 19th, 2019 Nature Communications published a peer-reviewed paper, “The flavonoid 4,4′-dimethoxychalcone promotes autophagy-dependent longevity across species” authored by Samsara’s scientific team. The paper demonstrates the capability of the Samsara platform to identify novel MoA geroprotective small molecules that extend healthy lifespan across species and which are protective in mammalian models of disease.

The particular molecule (4,4’-dimethoxychalcone) is a natural product derived from the Japanese longevity herb known as Ashitaba, consumed on the island of Okinawa, which hosts the greatest number of ultra-long-lived supercentenarians. Samsara Therapeutics is conducting medicinal chemistry optimization of this compound and other Samsara platform-identified compounds in collaboration with Evotec.

https://www.businesswire.com/news/home/20190226005495/en/Samsara-Therapeutics-Closes-Seed-Round-Led-by-Apollo-Ventures

The flavonoid 4,4′-dimethoxychalcone promotes autophagy-dependent longevity across species

Ageing constitutes the most important risk factor for all major chronic ailments, including malignant, cardiovascular and neurodegenerative diseases. However, behavioural and pharmacological interventions with feasible potential to promote health upon ageing remain rare. Here we report the identification of the flavonoid 4,4′-dimethoxychalcone (DMC) as a natural compound with anti-ageing properties. External DMC administration extends the lifespan of yeast, worms and flies, decelerates senescence of human cell cultures, and protects mice from prolonged myocardial ischaemia. Concomitantly, DMC induces autophagy, which is essential for its cytoprotective effects from yeast to mice. This pro-autophagic response induces a conserved systemic change in metabolism, operates independently of TORC1 signalling and depends on specific GATA transcription factors. Notably, we identify DMC in the plant Angelica keiskei koidzumi , to which longevity- and health-promoting effects are ascribed in Asian traditional medicine. In summary, we have identified and mechanistically characterised the conserved longevity-promoting effects of a natural anti-ageing drug.

https://www.nature.com/articles/s41467-019-08555-w

In a recent study, Zhang and his team from Guangzhou Medical University have investigated a potential therapeutic for Parkinson’s disease called 4,4-dimethoxychalcone, or DMC, which protects and promotes regeneration in cells. “In this study, we mainly focus on how to delay or attenuate dopaminergic neuron degeneration by using DMC,” stated Zhang.

Addressing concerns of DMC toxicity, the group showed that DMC conjugated to RVG is less toxic to cells than DMC alone. Furthermore, organs apart from the brain were not obviously adversely affected by DMC-RVG treatment.

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A related flavonoid has similar effects (4,4, not 3,4 dimethylchalcone)…

Notably, we identify DMC in the plant Angelica keiskei koidzumi , to which longevity- and health-promoting effects are ascribed in Asian traditional medicine.

Angelica koidzumi is available as “Japanese Ashitaba”.

https://www.swansonvitamins.com/p/swanson-premium-full-spectrum-japanese-ashitaba-500-mg-60-caps

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New paper:

The geroprotective potential of chalcones

Aging is the most important risk factor for multiple pathologies including cardiovascular, neoplastic, metabolic and neurodegenerative diseases. Potential geroprotective strategies involve lifestyle-related, nutritional and pharmacological interventions. Recently, chalcones, a subgroup of secondary plant metabolites, have gained attention. 4,4’-dimethoxychalcone was the first chalcone to be shown to mediate geroprotection and lifespan extension across different species. Several other chalcones also exert anti-aging effects at the cellular and organismal levels. Defined mechanistic routes that are causally involved in these protective effects have been delineated. Here, we summarize current evidence supporting the potential of 4,4’-dimethoxychalcone and other chalcones as geroprotective agents.

Full paper (Open Access): The geroprotective potential of chalcones | Nature Communications

AI Summary and review of practical implications for this line of research:

Here’s a summary of the paper “The geroprotective potential of chalcones” (Carmona-Gutierrez et al., Nature Communications, 2025) plus some thoughts about its practical implications.


Summary

This article is a review / perspective rather than a new experimental report. Its focus is on summarizing and synthesizing existing evidence about the potential of chalcones (a subclass of polyphenolic compounds) as geroprotective (i.e. anti-aging / healthspan-promoting) agents. (Nature)

Key Points

  1. Aging, caloric restriction mimetics, and autophagy

    • Aging is a major risk factor for many chronic diseases (cardiovascular, metabolic, neurodegenerative, cancer). (Nature)
    • One of the more promising anti-aging strategies is caloric restriction (CR), which triggers conserved cellular stress-response pathways. (Nature)
    • Because long-term CR is hard to maintain, researchers are interested in CR mimetics (CRMs): compounds that mimic beneficial effects of CR without reducing intake. (Nature)
    • A common mechanistic theme among CRMs is induction of autophagy, the cell’s recycling machinery. (Nature)
  2. Chalcones: definition, background, and interest

    • Chalcones are small molecules (α,β-unsaturated ketone core linking two aromatic rings) and a subclass of polyphenols. (Nature)
    • Many natural chalcones are known for anti-inflammatory, antioxidant, anticancer, and metabolic effects. (Nature)
    • Because of their relatively simple structure and synthetic accessibility, they are good starting points (scaffolds) for medicinal chemistry efforts. (Nature)
  3. Representative “hit” molecules and mechanistic insights

    The review highlights several chalcones with promising anti-aging / protective properties, along with mechanistic clues:

    • 4,4’-Dimethoxychalcone (4,4’-DMC)

      • Initially discovered from a flavonoid screening in yeast (promoting survival under aging-stress). (Nature)
      • Extended lifespan/health markers in multiple models (yeast, nematodes, Drosophila, mammalian cells). (Nature)
      • Induces autophagy; this effect is critical for its geroprotective impact (i.e. knocking out autophagy genes abrogates benefit). (Nature)
      • Mechanistically, 4,4’-DMC appears to inhibit a subset of GATA transcription factors, which are negative regulators of autophagy in certain contexts. (Nature)
      • Also, it modulates iron homeostasis/ferritinophagy and redox systems (e.g. via NRF2 / HMOX1 pathways), and has been implicated in ferroptosis in cancer or senescent cells. (Nature)
      • In older mice, chronic treatment reduced senescent cell burden in the liver, improved motor coordination, and prevented hair loss. (Nature)
    • 3,4-Dimethoxychalcone (3,4-DMC)

      • A stereoisomer of 4,4’-DMC, but with a distinct mechanistic signature: its pro-autophagy action relies on TFEB / TFE3 activation (transcription regulators of lysosomal/autophagic genes). (Nature)
      • In mice, 3,4-DMC increased autophagic flux in organs like heart and liver, and conferred partial cardioprotective effects in ischemia-reperfusion models. (Nature)
      • But caution: in some late phases of reperfusion, excessive autophagy (autosis) may be harmful, so timing matters. (Nature)
      • In cancer models, 3,4-DMC synergized with chemotherapy in an autophagy-dependent manner. (Nature)
      • Also, it showed protective effects in neurological injury, vascular disease, skin damage, etc. (Nature)
    • Other chalcones

      • The review surveys a broad set of chalcones (e.g. butein, licochalcone A, isobavachalcone, HSYA) with reported protective effects in models of neurodegeneration, inflammation, metabolic disease, UV-damage, etc. (Nature)
      • Some act via TFEB / autophagy pathways; others via antioxidant, anti-inflammatory, metabolic (AMPK) signaling, or modulation of sex-steroid pathways (some chalcones are estrogenic or anti-estrogenic). (Nature)
  4. Caveats, challenges, and outlook

    • Most data come from non-mammalian models or cell culture; longevity data in mammals are limited. (Nature)
    • Challenges include bioavailability, metabolism, pharmacokinetics, and safety / toxicity in long-term use. Many polyphenols are poorly absorbed or rapidly metabolized. (Nature)
    • Sex differences, hormonal interactions (some chalcones modulate estrogen or androgen signaling), and tissue specificity are underexplored. (Nature)
    • The proximal molecular targets (i.e., what proteins chalcones bind directly) are often unknown, complicating rational drug development. (Nature)
    • The authors suggest that more effort should go into structure–activity optimization, improving pharmacokinetics, and preclinical mammalian testing. (Nature)

Thus, the review articulates a compelling case that chalcones are promising natural/synthetic scaffolds for geroprotection, summarizes mechanistic routes (autophagy induction, redox regulation, iron metabolism, transcriptional control), and lays out challenges for translational progress.


Potential Practical Implications

Given the evidence and ideas in the review, here are some of the practical implications or translational opportunities that could follow from this line of research.

Domain Possible Application / Translation Key Opportunities & Challenges
Geroprotective therapeutics / anti-aging interventions Develop chalcone-derived drugs (or optimized analogs) that improve healthspan or mitigate age-related diseases in humans Major challenge: long-term safety, tolerability, dose scheduling, ensuring beneficial effects (without promoting unwanted cell proliferation, etc.)
Adjunct therapies in age-associated disease Use chalcones in conditions such as cardiovascular disease, metabolic syndrome, neurodegeneration, cancer, or ischemia-reperfusion injury For example, 3,4-DMC’s beneficial effects in myocardial injury or in neuroprotection suggest that localized / short-term chalcone therapy might be feasible
Senolytic / senostatic agents Some chalcones (notably 4,4’-DMC) appear capable of reducing senescent cell burden, possibly via ferritinophagy / ferroptosis pathways Could supplement or compete with existing senolytics (dasatinib + quercetin etc.) — needs validation in mammals, better delivery, specificity
Combination therapy / chemosensitization Chalcones like 3,4-DMC augmented chemotherapy efficacy in tumor models in an autophagy-dependent manner Potential to use chalcones as adjuvants in cancer therapy; careful modulation to avoid risks of autophagy in tumor survival
Topical / localized protection Because many chalcones have antioxidant, anti-inflammatory, and autophagy-stimulating effects, they might be used in skin (photoaging, UV damage), neural injury, ischemia zones etc. Topical delivery may mitigate systemic PK/toxicity issues; localized dosing reduces risk
Nutraceutical / dietary enhancement Some chalcones are present in food, herbs, and traditional medicines — the line between “supplement” and “drug” could be explored Must be wary of dose, purity, regulatory limits; also, metabolism may render many ineffective at physiological doses
Drug development scaffolds The chalcone core is synthetically tractable; medicinal chemistry could generate derivatives with better potency, selectivity, and pharmacokinetics Structure–activity relationship (SAR) studies, target deconvolution (identifying binding proteins), and delivery formulation innovations (e.g. nanoparticles, prodrugs) are open areas
Research tools / probes Chalcones (or derivatives) could be used as molecular probes to modulate autophagy, redox signaling, GATA/TFEB pathways in cell/animal models Useful for mechanistic biology studies, mapping aging pathways, screening for synergy with other geroprotectors

Thoughts & Caveats (from a translational perspective)

While the promise is exciting, there are several caveats and practical challenges to be aware of:

  1. Dose, exposure, and human pharmacokinetics

    • Many polyphenols / plant-derived compounds have low bioavailability, rapid metabolism, or poor tissue penetration.
    • To be effective, chalcone derivatives may need structural optimization (e.g. prodrugs, lipid forms, nanoparticle delivery) to reach effective concentrations in target tissues.
  2. Safety and specificity

    • Long-term modulation of autophagy or redox pathways can have dual effects. Too much autophagy (or in the wrong context) might cause cell death (e.g. autosis).
    • Because chalcones can also modulate hormone receptors (e.g. estrogenic/anti-estrogenic effects), there is risk of off-target endocrine effects.
    • Some chalcones might affect proliferative signaling; in older tissues or pre-cancerous lesions this may carry risk.
  3. Target validation and molecular specificity

    • A recurring problem is that for many chalcones, the direct molecular targets (proteins that bind them) are unknown or poorly defined. This makes rational design and off-target screening harder.
    • Without knowing the binding partners, it’s challenging to predict side-effects, resistance, or tissue specificity.
  4. Inter-species translation

    • Many anti-aging effects are demonstrated in yeast, worms, flies, or limited rodent models. Translating benefits to humans (long lifespan, diverse physiology) is nontrivial.
    • Effects may vary by sex, genetic background, diet, or comorbidities, so designing human studies is complex.
  5. Regulation, manufacturing, and commercialization

    • For compounds with dietary origins, the boundary between nutraceutical and drug is blurry; regulatory pathways (FDA, EMA) require well-defined safety/efficacy standards.
    • Scalable, pure, stable formulations would be needed for long-term human trials.
  6. Combination interactions and context-dependence

    • Because aging is multifactorial, chalcones will likely need to be part of combination regimens (with other CRMs, lifestyle interventions). Understanding synergy or antagonism is critical.
    • Timing and dosing are key: chronic vs intermittent dosing may have different effects; in particular, overactivation of autophagy or stress pathways in aged tissues might have detrimental effects.

If you like, I can pull out the top 2–3 chalcone derivatives from this review that seem most promising for clinical / translational development, and map out a hypothetical path (e.g. preclinical → human) for one of them. Would you like me to do that?

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